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The Organometallic Reader | Dedicated to the teaching and learning of modern organometallic chemistry.
Dedicated to the teaching and learning of modern organometallic chemistry. Famously do so. Almost by definition, metal alkyls contain a nucleophilic bond the M C bond! This bond can be so polarized toward carbon, in fact, that it can promote the elimination of some of the world’s worst leaving groups, like H and CH. Comparing organic and organometallic β-eliminations. A nucleophilic bond or lone pair promotes loss or migration of a leaving group. Written by Michael Evans. September 1, 2013 at 12:47 am.
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Organometallic Chemistry News
Thursday, July 10, 2014. Cu-Catalyzed Cascades to Carbocycles: Union of Diaryliodonium Salts with Alkenes or Alkynes Exploiting Remote Carbocations. Fengzhi Zhang, Shoubhik Das, Andrew J. Walkinshaw, Alicia Casitas, Michael Taylor, Marcos G. Suero, and Matthew J. Gaunt. J Am Chem. Soc. 25), pp 8851–8854. What do you think? Scandium-Catalyzed Cascade Cyclization to Produce Cyclobutane-Fused Tetrahydroquinoline, Chromane, Thiochromane, and Tetrahydronaphthalene Derivatives. What do you think? 21), pp 7563&...
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