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Philosophy to Chemistry to Elucidation

A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc.

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Philosophy to Chemistry to Elucidation | philosophytochemistrytoelucidation.blogspot.com Reviews
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Philosophy to Chemistry to Elucidation | philosophytochemistrytoelucidation.blogspot.com Reviews

https://philosophytochemistrytoelucidation.blogspot.com

A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc.

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Philosophy to Chemistry to Elucidation: February 2011

http://philosophytochemistrytoelucidation.blogspot.com/2011_02_01_archive.html

Philosophy to Chemistry to Elucidation. A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc. Tuesday, February 22, 2011. Logic Puzzle #13: Extra Correlations on the HSQC Spectrum. A 1H-13C HSQC is frequently used to assist in assigning a carbon as  CH, CH2 or CH3. The purpose of this puzzle is to examine a non-standard assignment. Wednesday, February 9, 2011. Blog on Hiatus from February 7 to 18, 2011. Stay tuned for more logic puzzles. Blog on Hiatus from F...

2

Philosophy to Chemistry to Elucidation: January 2010

http://philosophytochemistrytoelucidation.blogspot.com/2010_01_01_archive.html

Philosophy to Chemistry to Elucidation. A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc. Tuesday, January 26, 2010. Correlating 1D NMR data on an HMBC. There are many challenges present in deciphering correlations on an HMBC experiment. Barring any data collection issues, most of the challenges will arise from signals that are overlapping, thus, adding an element of ambiguity.  . Correlating 1D NMR data on an HMBC. Wednesday, January 20, 2010. The proces...

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Philosophy to Chemistry to Elucidation: February 2010

http://philosophytochemistrytoelucidation.blogspot.com/2010_02_01_archive.html

Philosophy to Chemistry to Elucidation. A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc. Tuesday, February 23, 2010. Ah Sugar, Sugar … Residue. An example sugar, phenyl hexapyranoside, with 13C chemical shifts is presented below. Ah Sugar, Sugar … Residue. Sugar residues can be tough to elucidate. They tend to have 1H NMR spectrum with overlapping and sometimes poorly-resolved 1H signals, and the 2D NMR data presents lots of ambiguous assignments&#46...

4

Philosophy to Chemistry to Elucidation: June 2010

http://philosophytochemistrytoelucidation.blogspot.com/2010_06_01_archive.html

Philosophy to Chemistry to Elucidation. A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc. Tuesday, June 29, 2010. Logic Puzzle #4: Correlating to the Correct 13C Signal. The goal of this puzzle is to resolve the ambiguity exhibited within a 2D NMR spectrum and thus provide the correct signal correlation. Note: the blue line was added to help align the correlation to the F1 domain. Logic Puzzle #4: Correlating to the Correct 13C Signal. In this puzzle, let...

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Philosophy to Chemistry to Elucidation: November 2010

http://philosophytochemistrytoelucidation.blogspot.com/2010_11_01_archive.html

Philosophy to Chemistry to Elucidation. A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc. Tuesday, November 30, 2010. Logic Puzzle #10: Deciphering the Fragment Pattern using 2D NMR Data. The goal of this puzzle is to conceptualize a fragment(s). From the given information. In the following example, a set of protonated sp3 carbons were extracted from an HSQC experiment (not shown). The green arrows represent the 2-3. Thursday, November 25, 2010. At 493, 2...

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Philosophy to Chemistry to Elucidation. A science blog on the process of structure elucidation using NMR, MS, UV/vis, IR, GC/LC, pXRD, etc. Tuesday, March 1, 2011. Logic Puzzle #13: Extra Correlations on the HSQC Spectrum … Solution. The intensity of a correlation in relation to other correlations on a 2D NMR spectrum can be just as important in a structure elucidation as assessing the position and phase of a correlation. The example below presents one such case. Tuesday, February 22, 2011. It’s be...

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